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Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of alpha,beta-Unsaturated Ketones 期刊论文

编号：

8c929036-7e80-47b9-892a-5a7b2009816e
作者：

Zhang Xin#^[2]Feng Xiujuan(冯秀娟)*^[1]Liu Hesong(刘鹤松)*^[3]Qin Yuhu^[1];Dai Yao^[1];
语种：

中文
期刊：

CHINESE JOURNAL OF CATALYSIS ISSN：0253-9837 2012 年 33 卷 3 期 (523 - 529) ; MAR
收录：
关键词：

benzyl chloride carbon monoxide allyltributylstannane coupling alpha,beta-unsaturated ketone
摘要：

Palladium-catalyzed three-component coupling reactions of benzyl chlorides, allyltributylstannane, and carbon monoxide were investigated. These three-component coupling reactions proceeded smoothly in the presence of Pd(PPh3)(4) to give benzyl allyl ketone products, which could transform to alpha,beta-unsaturated ketone compounds 6a-6n after purification via basic alumina column chromatography. alpha,beta-Unsaturated ketone compounds 6b, 6d-h, 6j, 5l, and 6l-6n are unknown compounds, and their structure was characterized by infrared spectroscopy, H-1 nuclear magnetic resonance spectroscopy, C-13 nuclear magnetic resonance spectroscopy, and high-resolution mass spectroscopy.
推荐引用方式
GB/T 7714：

Zhang Xin,Feng Xiujuan,Liu Hesong, 等. Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of alpha,beta-Unsaturated Ketones [J].CHINESE JOURNAL OF CATALYSIS,2012,33(3):523-529.
APA：

Zhang Xin,Feng Xiujuan,Liu Hesong,Qin Yuhu,&Dai Yao.(2012).Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of alpha,beta-Unsaturated Ketones .CHINESE JOURNAL OF CATALYSIS,33(3):523-529.
MLA：

Zhang Xin, et al. "Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of alpha,beta-Unsaturated Ketones" .CHINESE JOURNAL OF CATALYSIS 33,3(2012):523-529.
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