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Enantioselective transesterification of (R, S)-2-pentanol catalyzed by a new flower-like nanobioreactor 期刊论文

编号：

91342db1-1b34-476a-a651-0403ec2b6828
作者：

Wu, Zhuofu#^[1,2]Li, Xiang^[3];Li, Fuguang(李付光)^[4]Yue, Hong^[1];He, Chengyan^[2];Xie, Feng(谢风)*^[2]Wang, Zhi(王智)*^[1]
语种：

英文
期刊：

RSC ADVANCES ISSN：2046-2069 2014 年 4 卷 64 期 (33998 - 34002) ; 2014
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摘要：

The lipase-incorporated nanoflower was prepared and used for resolution of (R, S)-2-pentanol with vinyl acetate as an acyl donor in organic solvents. SEM images indicated that the lipase-incorporated nanoflower had high surface area which was favourable for mass transfer. The FTIR spectrum identified the presence of the lipase in the nanoflower. The lipase-incorporated nanoflower could display its maximum enzyme activity (22.5 mu mol h(-1) mg(-1)) and good enantioselectivity (E value, 47.3) under the optimal reaction conditions (in cyclohexane at 60 degrees C and water activity of 0.10). After ten continuous batches, the nanoflower retained 98.7% of the initial enzyme activity and 95.6% of the initial enantioselectivity.
推荐引用方式
GB/T 7714：

Wu Zhuofu,Li Xiang,Li Fuguang, et al. Enantioselective transesterification of (R, S)-2-pentanol catalyzed by a new flower-like nanobioreactor [J].RSC ADVANCES,2014,4(64):33998-34002.
APA：

Wu Zhuofu,Li Xiang,Li Fuguang,Yue Hong,&Wang Zhi.(2014).Enantioselective transesterification of (R, S)-2-pentanol catalyzed by a new flower-like nanobioreactor .RSC ADVANCES,4(64):33998-34002.
MLA：

Wu Zhuofu, et al. "Enantioselective transesterification of (R, S)-2-pentanol catalyzed by a new flower-like nanobioreactor" .RSC ADVANCES 4,64(2014):33998-34002.
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